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  1. Journal of the American Oil Chemists' Society
  2. Journal of the American Oil Chemists' Society : Volume 80
  3. Journal of the American Oil Chemists' Society : Volume 80, Issue 2, February 2003
  4. Noncatalytic alcoholysis kinetics of soybean oil
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Journal of the American Oil Chemists' Society : Volume 94
Journal of the American Oil Chemists' Society : Volume 93
Journal of the American Oil Chemists' Society : Volume 92
Journal of the American Oil Chemists' Society : Volume 91
Journal of the American Oil Chemists' Society : Volume 90
Journal of the American Oil Chemists' Society : Volume 89
Journal of the American Oil Chemists' Society : Volume 88
Journal of the American Oil Chemists' Society : Volume 87
Journal of the American Oil Chemists' Society : Volume 86
Journal of the American Oil Chemists' Society : Volume 85
Journal of the American Oil Chemists' Society : Volume 84
Journal of the American Oil Chemists' Society : Volume 83
Journal of the American Oil Chemists' Society : Volume 82
Journal of the American Oil Chemists' Society : Volume 81
Journal of the American Oil Chemists' Society : Volume 80
Journal of the American Oil Chemists' Society : Volume 80, Issue 12, December 2003
Journal of the American Oil Chemists' Society : Volume 80, Issue 11, November 2003
Journal of the American Oil Chemists' Society : Volume 80, Issue 10, October 2003
Journal of the American Oil Chemists' Society : Volume 80, Issue 9, September 2003
Journal of the American Oil Chemists' Society : Volume 80, Issue 8, August 2003
Journal of the American Oil Chemists' Society : Volume 80, Issue 7, July 2003
Journal of the American Oil Chemists' Society : Volume 80, Issue 6, June 2003
Journal of the American Oil Chemists' Society : Volume 80, Issue 5, May 2003
Journal of the American Oil Chemists' Society : Volume 80, Issue 4, April 2003
Journal of the American Oil Chemists' Society : Volume 80, Issue 3, March 2003
Journal of the American Oil Chemists' Society : Volume 80, Issue 2, February 2003
Comparison of four analytical methods for the determination of peroxide value in oxidized soybean oils
Physical and textural characteristics of hydrogenated low-erucic acid rapeseed oil and low-erucic acid rapeseed oil blends
Simultaneous determination of ascorbyl palmitate and nine phenolic antioxidants in vegetable oils and edible fats by HPLC
How green is green? Long-term relationships between green seeds and chlorophyll in canola grading
Specific heats of cottonseed and its co-products
Phospholipid class and FA compositions of modified soybeans processed with two extraction methods
Effect of enzymatic transesterification with flaxseed oil on the high-melting glycerides of palm stearin and palm olein
Study on synthesis parameters of lipase-catalyzed hexyl acetate in supercritical CO$_{2}$ by response surface methodology
Biosynthesis of tetrahydrofuranyl fatty acids from linoleic acid by clavibacter sp. ALA2
Relationship between rancimat and active oxygen method values at varying temperatures for several oils and fats
Extraction of wheat germ oil by supercritical CO$_{2}$: Oil and defatted cake characterization
Effect of a modified deep-fat fryer on chemical and physical characteristics of frying oil
Protein enrichment of defatted salicornia meal by air classification
Oxidative and flavor stabilities of soybean oils with low-and ultra-low-linolenic acid composition
Volatile by-products during heat polymerization of soybean oil
Influence of operation variables on quality parameters of olive husk oil extracted with CO$_{2}$: Three-step sequential extraction
Noncatalytic alcoholysis kinetics of soybean oil
Journal of the American Oil Chemists' Society : Volume 80, Issue 1, January 2003
Journal of the American Oil Chemists' Society : Volume 79
Journal of the American Oil Chemists' Society : Volume 78
Journal of the American Oil Chemists' Society : Volume 77
Journal of the American Oil Chemists' Society : Volume 76
Journal of the American Oil Chemists' Society : Volume 75
Journal of the American Oil Chemists' Society : Volume 74

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Noncatalytic alcoholysis kinetics of soybean oil

Content Provider SpringerLink
Author Dasari, Mohanprasad A. Goff, Michael J. Suppes, Galen J.
Copyright Year 2003
Abstract Reaction kinetics for the alcoholysis of soybean oil with methanol, ethanol, and isopropanol were evaluated in the absence of catalyst. Metal reactor surfaces catalyzed these reactions, so the reactions were conducted in glass capillary tubes at 120, 150, and 180°C. The reactivity of the alcohols increased with decreasing carbon number. Higher temperatures promoted faster reactions. Higher alcohol stoichiometries did not significantly increase reaction rates; this was attributed to the limited solubility of the alcohol in the soybean oil. At less than 20% conversion, the solubility of the alcohol in the oil phase continuously increased, resulting in increased reaction rates. At approximately 20% conversion, the reaction systems became homogeneous until a glycerine phase was formed at high conversions. In addition to their fundamental value, these data provided a basis on which catalytic reactions can be investigated between 100 and 200°C.
Starting Page 189
Ending Page 192
Page Count 4
File Format PDF
ISSN 0003021X
Journal Journal of the American Oil Chemists' Society
Volume Number 80
Issue Number 2
e-ISSN 15589331
Language English
Publisher Springer-Verlag
Publisher Date 2003-01-01
Publisher Place Berlin, Heidelberg
Access Restriction One Nation One Subscription (ONOS)
Subject Keyword Biodiesel methyl esters noncatalytic reactions soybean oil alcoholysis trigylceride Chemistry/Food Science Analytical Chemistry Biotechnology Industrial Chemistry/Chemical Engineering Biomaterials Agriculture
Content Type Text
Resource Type Article
Subject Organic Chemistry Chemical Engineering
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