NDLI: Synthesis, Structure, and Biological Activity of [2.2]Paracyclophane Derivatives. 8. α-Pyridyl([2.2]paracyclophan-4-yl)-phenylmethanol: Structure of the Complex with Cu(II) Chloride and Intramolecular Cyclization

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Synthesis, Structure, and Biological Activity of [2.2]Paracyclophane Derivatives. 8. α-Pyridyl([2.2]paracyclophan-4-yl)-phenylmethanol: Structure of the Complex with Cu(II) Chloride and Intramolecular Cyclization

Synthesis and Structure Elucidation of 1-Aryl-substituted Tetrahydropyridone Derivatives

Ambidentate Properties of Asymmetric Substituted Imidazoles. Direction of Benzylation of 2-[N-(4-Chlorophenyl)carbamoyl]methylthio-4-phenyl-1H-imidazole

Synthesis of 5-(Arylamino)-1-benzyluracils

Sulfenyl Halides in the Synthesis of Heterocycles. 2. Cyclization in Reactions of Hetarenesulfenyl Chlorides with 3,3-Dimethyl-1-butene

Synthesis of 6-Methylbenzo-[b]pyrido[3,2-f][1,6]naphthyridines from 4-Chloro-2-methylquinoline

Reaction of 2-Aryl-5-R-5,6-dihydro-7H-[1,2,4]-triazolo[5,1-b][1,3]thiazin-7-ones with Aryl Bromomethyl Ketones and Benzyl Bromide

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Rearrangement of 2-Amino-4-cyclopropylthiazolium Bromide

Unexpected Synthesis of Substituted 9b,9c-Dihydro-5-oxa-2-azacyclopenta[2,3]cyclopropa[1,2-a]naphthalene-1,3,4-triones According to a Modified Reformatsky Reaction

A Novel Heterocyclic System: Benzo[b]furo[4,3,2-ef][1]benzoxepin

1-(3-Chloropropyl)-3-phenylbenzothieno-[2,3-c]pyridine: an Intermediate in Synthesis of 5-Phenylbenzothieno[2,3-e]indolizinium Salts

First Example of Synthesis of Thieno[2,3-d]pyrimidine-6-carbaldehydes by Oxidation of Thieno[2,3-d]pyrimidin-6-yl Methanols with Molecular Iodine

Synthesis of a Novel Heterocyclic System: 3-Chloro-7,8-dihydro[1,4]dioxino[2″,3″:4′,5′]benzo[4,5]imidazo[1,2-c][1,2,3]thiadiazole

Arylamination of 1,2,5-Thiadiazol-3-yl Trifluoromethanesulfonate

Annelation of the Norbornene Skeleton in Reactions of Hetarene Sulfenyl Chlorides with Norbornadiene

Chemistry of Heterocyclic Compounds : Volume 41, Issue 5, May 2005

Chemistry of Heterocyclic Compounds : Volume 41, Issue 4, April 2005

Chemistry of Heterocyclic Compounds : Volume 41, Issue 3, March 2005

Chemistry of Heterocyclic Compounds : Volume 41, Issue 2, February 2005

Chemistry of Heterocyclic Compounds : Volume 41, Issue 1, January 2005

Chemistry of Heterocyclic Compounds : Volume 40

Chemistry of Heterocyclic Compounds : Volume 39

Chemistry of Heterocyclic Compounds : Volume 38

Chemistry of Heterocyclic Compounds : Volume 37

Chemistry of Heterocyclic Compounds : Volume 36

Chemistry of Heterocyclic Compounds : Volume 35

Chemistry of Heterocyclic Compounds : Volume 34

Chemistry of Heterocyclic Compounds : Volume 33

Synthesis, Structure, and Biological Activity of [2.2]Paracyclophane Derivatives. 8. α-Pyridyl([2.2]paracyclophan-4-yl)-phenylmethanol: Structure of the Complex with Cu(II) Chloride and Intramolecular Cyclization

Content Provider	SpringerLink
Author	Kryvenko, L. I. Zvolinskii, O. V. Soldatenkov, A. T. Kurbatova, A. I. Dorofeeva, G. I. Kuleshova, L. N. Khrustalev, V. N.
Copyright Year	2005
Abstract	The reaction of 2-benzoylpyridine with 4-([2.2]paracyclophanyl)lithium or of 4-benzoyl[2.2]paracyclophane with 2-pyridyllithium gave α-pyridyl([2.2]paracyclophan-4- yl)phenylmethanol. X-ray analysis has been used to study the molecular and crystalline structure of its complex with Cu(II) chloride. It was found that this triaryl-substituted methanol undergoes an intramolecular cyclocondensation in refluxing formic acid and involves the pyridine ring and the cyclophane substituent. Heterocyclization at the ortho-position of the latter gives 10-phenyl[2.2]paracyclophano[4,5-b]indolizine and cyclization at the pseudo-gem-position the 1-phenyl-1,1a-dehydro-6-aza[3.2.2](1,2,5)-6H-cyclophano[1,2-a]pyridine. The compounds prepared have luminescent properties.
Starting Page	745
Ending Page	753
Page Count	9
File Format	PDF
ISSN	00093122
Journal	Chemistry of Heterocyclic Compounds
Volume Number	41
Issue Number	6
e-ISSN	15738353
Language	English
Publisher	Kluwer Academic Publishers-Consultants Bureau
Publisher Date	2005-01-01
Publisher Place	New York
Access Restriction	Subscribed
Subject Keyword	α-pyridyl([2.2]paracyclophan-4-yl)phenylmethanol [2.2]paracyclophano[4,5-b]indolizine 1-phenyl-1,1a-dehydro-6-aza[3.2.2](1,2,5)-6H-cyclophano[1,2-a]pyridine complex with Cu(II) chloride heterocyclization luminescent properties Organic Chemistry Pharmacy
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Synthesis, structure, and biological activity of [2.2]paracyclophanes. 7. Synthesis of 2-([2.2]paracyclophan-4-yl)pyridines,-tetrahydroquinolines, and-benzo[h]quinolines based on condensation of 4-(β-dimethylaminopropionyl)[2.2]paracyclophane with primary amines

Indolopyridines with a bridging heteroatom : 10. Synthesis, structure, and acid catalyzed reactions of 1-([2.2]paracyclophan-4-yl)-1-(2-pyridyl)ethanol

Synthesis, structure, and biological activity of [2.2]paracyclophanes. 6. Synthesis of 2-([2.2]paracyclophan-4-yl)(benzo[g])indoles

Eine verbesserte Synthese von [2.2] Paracyclophan und 4-Formyl-[2.2] paracyclophan

Oxidation reactions of azines : 3. Synthesis and oxidation of 1,2,3,6-tetrahydro-4-([2.2]-Paracyclophan-4-yl)pyridines

Synthesis and molecular structure of the cobalt(ii) chloride complex with bis(α-pyridyl)-substituted bispidinoaza-14-crown-4

Quantitative Formation of a [2.2]Paracyclophane Derivative via Topochemical Photoreaction of Crystal Complex of Ethyl and Propyl α-Cyano-4-[2-(4-pyridyl)ethenyl]cinnamates

Diastereomers Composed of Two Planar-Chiral Subunits: Bis([2.2]paracyclophan-4-yl)methane and Analogues

Synthesis, spectroelectrochemistry and electronic structure calculations of 4-(2-ferrocenylvinyl)-[2.2]-paracyclophane and 4,12-di-(2-ferrocenylvinyl)-[2.2]-paracyclophane

Synthesis, Structure, and Biological Activity of [2.2]Paracyclophane Derivatives. 8. α-Pyridyl([2.2]paracyclophan-4-yl)-phenylmethanol: Structure of the Complex with Cu(II) Chloride and Intramolecular Cyclization

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