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  1. Monatshefte für Chemie - Chemical Monthly
  2. Monatshefte für Chemie - Chemical Monthly : Volume 144
  3. Monatshefte für Chemie - Chemical Monthly : Volume 144, Issue 3, March 2013
  4. Kinetics and mechanism of oxidation of alcohols
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Monatshefte für Chemie - Chemical Monthly : Volume 148
Monatshefte für Chemie - Chemical Monthly : Volume 147
Monatshefte für Chemie - Chemical Monthly : Volume 146
Monatshefte für Chemie - Chemical Monthly : Volume 145
Monatshefte für Chemie - Chemical Monthly : Volume 144
Monatshefte für Chemie - Chemical Monthly : Volume 144, Issue 12, December 2013
Monatshefte für Chemie - Chemical Monthly : Volume 144, Issue 11, November 2013
Monatshefte für Chemie - Chemical Monthly : Volume 144, Issue 10, October 2013
Monatshefte für Chemie - Chemical Monthly : Volume 144, Issue 9, September 2013
Monatshefte für Chemie - Chemical Monthly : Volume 144, Issue 8, August 2013
Monatshefte für Chemie - Chemical Monthly : Volume 144, Issue 7, July 2013
Monatshefte für Chemie - Chemical Monthly : Volume 144, Issue 6, June 2013
Monatshefte für Chemie - Chemical Monthly : Volume 144, Issue 5, May 2013
Monatshefte für Chemie - Chemical Monthly : Volume 144, Issue 4, April 2013
Monatshefte für Chemie - Chemical Monthly : Volume 144, Issue 3, March 2013
Solution-processed copper zinc tin sulfide thin films from metal xanthate precursors
Heptanuclear zinc cluster for growth of zincite and manganese-doped zincite thin films for sensor applications
Phase analysis and volume properties of the (LiF–NaF–KF)eut–K2ZrF6 system
Kinetic and equilibrium studies of σ-adduct formation and nucleophilic substitution in the reactions of 2-chloro-3,5-dinitropyridine and 2-ethoxy-3,5-dinitropyridine with p-substituted anilines in DMSO
Kinetics and mechanism of oxidation of alcohols
Synthesis and antimicrobial activity of novel gold(I) N-heterocyclic carbene complexes
Novel effect of palladium catalysts on chemoselective oxidation of β-pinene by hydrogen peroxide
Experimental and theoretical studies of Diels–Alder reaction between methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate and cyclopentadiene
One-pot synthesis of N-substituted 2,4-thiazolidinediones and computational investigation of the products
Synthesis of novel halogenated 2-vinylchroman-4-ones and their antimicrobial activity
A selective synthesis of β-isothiocyanato ketones through a Staudinger/aza-Wittig reaction of β-azido ketones
A green approach to the synthesis of chalcones via Claisen-Schmidt condensation reaction using cesium salts of 12-tungstophosphoric acid as a reusable nanocatalyst
Lewis basic ionic liquid as an efficient and facile catalyst for acetylation of alcohols, phenols, and amines under solvent-free conditions
An improved, safe, and efficient conversion of triarylpyrylium perchlorates to corresponding cyanodienones using Amberlite IRA 910[CN]
Direct asymmetric aldol reaction of cyclohexanone with aldehydes catalyzed by chiral trans-cyclohexanediamine l-tartrate salt
Trichloroisocyanuric acid-catalyzed one-pot synthesis of 2,4,5-trisubstituted imidazoles
A simple one-pot synthesis of quinoline-4-carboxylic acid derivatives by Pfitzinger reaction of isatin with ketones in water
Lewis acid catalyst free synthesis of substituted imidazoles in 2,2,2-trifluoroethanol
Carboxylic acid-catalyzed one-pot synthesis of cyanoacetylureas and their cyclization to 6-aminouracils in guanidine ionic liquid
Squaric acid catalyzed simple synthesis of N-substituted pyrroles in green reaction media
Magnesium bis(trifluoromethane)sulfonimide: an efficient catalyst for the synthesis of coumarins under solvent-free conditions
Cyclization of α,α′-bis(substituted-benzylidene)cyclohexanones and 4-hydroxycoumarin: synthesis of 11-benzylidene-8,9,10,11-tetrahydro-7-phenyl-6H,7H-chromeno[4,3-b]chromen-6-ones as new pyranochromene derivatives
Synthesis of a functionalized chromane derivative via a TiCl4-mediated cyclization reaction
Exploring 6-(substituted sulfonyl)imidazopyridines as a potential scaffold for the design of 5-HT6 ligands
An efficient synthesis of novel sucrose-containing dilactams
Monatshefte für Chemie - Chemical Monthly : Volume 144, Issue 2, February 2013
Monatshefte für Chemie - Chemical Monthly : Volume 144, Issue 1, January 2013
Monatshefte für Chemie - Chemical Monthly : Volume 143
Monatshefte für Chemie - Chemical Monthly : Volume 142
Monatshefte für Chemie - Chemical Monthly : Volume 141
Monatshefte für Chemie - Chemical Monthly : Volume 140
Monatshefte für Chemie - Chemical Monthly : Volume 139
Monatshefte für Chemie - Chemical Monthly : Volume 138
Monatshefte für Chemie - Chemical Monthly : Volume 137
Monatshefte für Chemie - Chemical Monthly : Volume 136
Monatshefte für Chemie - Chemical Monthly : Volume 135
Monatshefte für Chemie - Chemical Monthly : Volume 134
Monatshefte für Chemie - Chemical Monthly : Volume 133
Monatshefte für Chemie - Chemical Monthly : Volume 132
Monatshefte für Chemie - Chemical Monthly : Volume 131
Monatshefte für Chemie - Chemical Monthly : Volume 130
Monatshefte für Chemie - Chemical Monthly : Volume 129
Monatshefte für Chemie - Chemical Monthly : Volume 128

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Kinetics and mechanism of oxidation of alcohols

Content Provider SpringerLink
Author Laila, Abdulhameed
Copyright Year 2012
Abstract This paper describes the kinetics and mechanism of oxidation of several monohydric alcohols to the corresponding aldehydes and ketones by bis(quinuclidine)bromine(I) bromide in the presence of pyridinium trifluoroacetate. All evidence from the thermodynamic parameters, deuterium kinetic isotope effect, and Hammett reaction constants supports a two-step mechanism and suggests that the transfer of hydride ion from the substrate to the oxidant is the rate-determining step.
Starting Page 307
Ending Page 312
Page Count 6
File Format PDF
ISSN 00269247
Journal Monatshefte für Chemie - Chemical Monthly
Volume Number 144
Issue Number 3
e-ISSN 14344475
Language English
Publisher Springer Vienna
Publisher Date 2012-08-04
Publisher Place Vienna
Access Restriction One Nation One Subscription (ONOS)
Subject Keyword Carbonyl compounds Isotope effects Structure–reactivity relationship Rate constants Chemistry/Food Science Organic Chemistry Inorganic Chemistry Analytical Chemistry Physical Chemistry Theoretical and Computational Chemistry
Content Type Text
Resource Type Article
Subject Chemistry
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